There's no reason in my mind to continue to use MySQL except for legacy (software or people).
How about performance?
I'm working with a system that essentially does OLAP with a lot of updates. PostgreSQL (7.3.4) works great for it in theory, but in practice the system bogs down over a relatively short period of time (a few hours), and way down over the course of a day. We have to stop and vacuum the database nightly. A vaguely similar system I've worked on that uses MySQL (4.0.something with InnoDB tables) didn't suffer the same degradation.