create unique index left_ix on words(left)
or
create unique index left_ix on words(left, right)
(and their opposites).
The first form is more "correct" - you really only want the key in the index. The second form may give you slightly better performance, at the expense of allowing duplicate "left" words into the table as long as they point at a different "right" word, and slightly more work during inserts (index maintenance is a little more complicated).
Personally I'd use the first form (index on "left", and a separate index on "right").
Michael
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