I was playing around with this and noticed a harmless but problematic side-effect of the way you construct the hash.
%scores = (
map { $_ => 1 } qw( A E I L N O R S T U ),
map { $_ => 2 } qw( B D G ),
map { $_ => 3 } qw( C M P ),
map { $_ => 4 } qw( F H V W Y ),
map { $_ => 5 } qw( K ),
map { $_ => 8 } qw( J X ),
map { $_ => 10 } qw( Q Z ),
);
print join($", sort keys %scores), $/;
__END__
10 2 3 4 5 8 A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
Since you're filtering for letters, the numbers don't get picked up, but the maps are having a side-effect mapping of the other maps below them. Parens around the maps seems to fix it.
I also learned something from your example. I would have predicted that the last unless defined would not work right on empty input b/c $_ still contains a "\n" which would be defined. I would have been wrong.