Well for some reason, its not appearing in my client hello. Below is my code. With SSL_cipher_list set to ALL, i can see 38 cipher suites being sent but not the "TLS_EMPTY_RENEGOTIATION_INFO_SCSV". What OS and openssl version are you using?

#!/usr/bin/perl

 use IO::Socket::SSL;
 use IO::Socket qw(:DEFAULT :crlf);
 $/ = CRLF;
 $| = 1;
use warnings;
my $client = IO::Socket::SSL->new(PeerHost => "1.1.1.115", PeerPort =>
+ "443", SSL_verify_mode => SSL_VERIFY_NONE, SSL_cipher_list => 'ALL')
+;

    $msg1 = "GET /index.html HTTP/1.1".$/;
    $msg2 = "Host: windows".$/;
    $msg3 = "User-Agent: curl/7.18.1 (i386-redhat-linux-gnu) libcurl/7
+.18.1 NSS/3.12 Beta 3 zlib/1.2.3 libidn/0.6.14".$/;


    print $client $msg1,$msg2,$msg3.CRLF;

    shutdown($client,2);
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> With SSL_cipher_list set to ALL, i can see 38 cipher suites being sent but not the "TLS_EMPTY_RENEGOTIATION_INFO_SCSV".

With SSL_cipher_list ALL I get 91 ciphers and it includes TLS_EMPTY_RENEGOTIATION_INFO_SCSV. I'm using OpenSSL 1.0.1 on Linux. Having only this few ciphers in ALL looks for me like a very old OpenSSL version which might not even support TLS_EMPTY_RENEGOTIATION_INFO_SCSV. What version you are using? My guess is that you still might be using 0.9.8, probably on OS X which shipped this very old and for ages unsupported version by default.

The openssl version on my linux is 1.0.2j 26 Sep 2016 and i can send that TLS_EMPTY_RENEGOTIATION_INFO_SCSV if i use openssl commands.