NOTE: requires portfile to be in sorted order

NOTE: The IPfile read should be in the body of the "while", not in the condition.

NOTE: "goto" not required.

NOTE: Does not even have to read all the way through the IPfile if no IPs that are near the end are referenced.

#!/usr/bin/perl

use strict; # https://perlmonks.org/?node_id=11129698
use warnings;

@ARGV = qw( port.file ip.file out.file); # FIXME only for testing

@ARGV == 3 or die "wrong number of arguments";
open $_, '<', shift or die for my( $F0, $F1);
open $_, '>', shift or die for my $F2;
my ($no, $IP) = 0;
while( <$F0> ) # NOTE assumes port file is in sorted order
  {
  my ($stop, $port) = /^(\d+)\s+(.*\n)/;
  $no += ($IP = <$F1> // die) =~ /^(?:\d+\.){3}\d+\s+\z/ while $no < $
+stop;
  print $F2 $IP =~ s/\s+\z//r, "\t$port";
  }
close $F2;

system 'cat out.file'; # FIXME only for testing
[download]

Outputs (for your larger example with blank lines in the IP file):

1.0.0.29        80/tcp   closed http
1.0.0.29        443/tcp  closed https
1.0.0.29        8080/tcp open   http-proxy
1.0.0.49        80/tcp   open     http
1.0.0.49        443/tcp  filtered https
1.0.0.49        8080/tcp filtered http-proxy
1.0.0.69        80/tcp   open     http
1.0.0.69        443/tcp  filtered https
1.0.0.69        8080/tcp filtered http-proxy
[download]