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#!/usr/bin/perl

...
foreach my $cast ( $dom->find('table.cast_list > tr:not(:first-child)'
+)->each ){
  say trim ($cast->at('td:nth-of-type(2) > a')->text ) . ' as ' . trim
+ ( $cast->at('td.character')->all_text );
}

Caddyshack (1980)
Chevy Chase as Ty Webb
...
Ann Ryerson as Grace
Brian Doyle-Murray as Lou Loomis
Hamilton Mitchell as Motormouth