Here's another easy method:

$_ = <<EOF;
<xml>
 <email>toto@foo.com</email><name>Toto</name>
 <email>tata@bar.com</email><name>Tata</name>
 <email>tutu@baz.com</email><name>Tutu</name>
</xml>
EOF

my @email = /<email>(.*?)<\/email>/g;
my @name = /<name>(.*?)<\/name>/g;
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(Note that it leaves XML entities undecoded, as noted in the reply.)